The provided this procedure, to determine the purity of formaldehyde using a back-titration method with sodium hydroxide (NaOH) and hydrochloric acid (HCl).
APPARATUS
a). 250 ml Erlenmeyer flask.
b). 5 ml stoppered weighing bottle.
c). 100 ml measuring cylinder.
d). Burette.
REAGENTS
a). 1 (M) sodium sulfite solution.
b). 1.0 (N) standard hydrochloric acid (HCl).
c). Phenolphthalein indicator solution.
Purity of Formaldehyde ProcedureÂ
Take formaldehyde sample in a beaker and neutralize with 1(N) NaOH solution using phenolphthalein indicator.Â
Take 50 ml of 1 (M) sodium sulphite solution in a 250-ml Erlenmeyer flask.Â
Add 3 drops of phenolphthalein indicator and carefully neutralize by titration with 1.0(N) HCl solution till it becomes colorless.Â
Now take a neutral formaldehyde sample in a 5 ml stoppered weighing bottle.Â
From it transfer about 2 gm(accurately weighed) sample to the Erlenmeyer flask.Â
Put the stopper and shake properly for thorough mixing.Â
Titrate the resulting mixture slowly with standard 1.0 (N) HCl acid taken in a burette till complete deceleration.
1 ml 1(N) HCl acid = 0.03003 gm HCHO
Purity of formaldehyde (%) = Acid Titrate (ml) x normality of acid x 3.003/W
Wt of formaldehyde sample taken (gm)
Formaldehyde purity = 37- 40%